•W. Sprengel1, V. Barbe1, S. Herth1,2,
O. Gutfleisch3, R. Würschum4 und H.-E. Schaefer1
1Institut für Theoretische u. Angewandte Physik, Universität
Stuttgart, 70550 Stuttgart
2Institut für Nanotechnologie, Forschungszentrum Karlsruhe
GmbH, 76021 Karlsruhe
3Leibniz-Institut für Festkörper- und Werkstoffforschung
Dresden, 01171 Dresden
4Institut für Technische Physik, Technische Universität
Graz, 8010 Graz, Österreich
For nanocrystalline Nd-rich Nd2Fe14B the grain-boundary
self-diffusivities DGB of 59Fe and 147Nd
were studied by the radio tracer technique. In the case of 59Fe
the temperature dependence of the product of the interface thickness and
the interface diffusion coefficient,
dDGB,
shows a sharp increase for temperatures above 951 K where a liquid grain-boundary
phase has been reported. Below 951 K the temperature dependence of the
59Fe diffusivity can be described by an Arrhenius type behavior
[1]. First results of the 147Nd diffusion are presented.