2nd Internat. Symp. on SiAlONs and Non-Oxides, Mie, Japan,
02.12-05.12.2007
Surface Structuring of a/b-SiAlON Ceramics by Plasma-Etching
M. Riva*a, S. Holzer a, R. Oberacker a, M.J. Hoffmann a, C. Ziebert b
a Institute
for Ceramics in Mechanical Engineering, University of
76131 Karlsruhe, Germany
b Institute
for Materials Research I, Forschungszentrum Karlsruhe,
Hermann-von-Helmholtz-Platz 1,
76344 Eggenstein-Leopoldshafen
76021, Karlsruhe,
Germany
E-mail: marco.riva@ikm.uni-karlsruhe.de
The plasma-etching technique with a reactive gas is a
common practice to investigate the microstructure of Si3N4. In this case the b-grains show a greater etching
rate than the grain boundary glassy phase, so that they are preferentially
dissolved and the microstructure is revealed.
In this study it was tried to transfer this effect to
sialon ceramics but with the aim to create a height-relief in the surface with
the function of micro lubrication pockets for the application in
lubricated gliding systems.
During this study the effects of plasma etching on sialon
ceramics by CF4/O2 were investigated. It was shown
that b-grains exhibit a higher etching rate than the grain
boundary glassy phase or the a-grains, generating pockets in
a range of few µm. According to this, the bearing ratio of such a surface can
be adjusted by the relation of quantity of a/b-sialon and the depth of the lubrication pockets by etching parameters
like in this case the dwell time.
Therefore sialon samples with different a/b-ratio were produced and subsequently etched under
different conditions.
The so created surfaces were characterized both by
sScanning
electron microscopy (SEM) and by
atomic
force microscopy AFM (AFM)
analysisin contact mode.
These complementary techniques also enabled
the determination of the bearing ratio. Certain selected
compositions and etching conditions have been applied
on samples which were investigated in tribological measurements in self-mated
pair.